Given \(\epsilon > 0\text{,}\) let \(R\) be a closed rectangle that contains \(S\text{.}\) Let \(P\) be a partition of \(R\) such that
\begin{equation}
U(P,\chi_S) \leq \left( \int_R \chi_S \right) + \epsilon = V(S) + \epsilon
\qquad \text{and} \qquad
L(P,\chi_S) \geq \left( \int_R \chi_S \right) - \epsilon = V(S)-\epsilon.
\end{equation}
Let \(R_1,R_2,\ldots,R_k\) be all the subrectangles of \(P\) such that \(\chi_S\) is not identically zero on each \(R_j\text{.}\) That is, there is some point \(x \in R_j\) such that \(x \in S\) (i.e. \(\chi_S(x)=1\)). Let \(O_j\) be an open rectangle such that \(R_j \subset O_j\) and \(V(O_j) < V(R_j) + \nicefrac{\epsilon}{k}\text{.}\) Notice that \(S \subset
\bigcup_j O_j\text{.}\) Then
\begin{equation}
U(P,\chi_S) = \sum_{j=1}^k V(R_j) >
\left(\sum_{j=1}^k V(O_j)\right) - \epsilon \geq m^*(S) - \epsilon .
\end{equation}
As \(U(P,\chi_S) \leq V(S) + \epsilon\text{,}\) then \(m^*(S) - \epsilon \leq V(S) + \epsilon\text{,}\) or in other words \(m^*(S) \leq V(S)\text{.}\)
Let
\(R'_1,R'_2,\ldots,R'_\ell\) be all the subrectangles of
\(P\) such that
\(\chi_S\) is identically one on each
\(R'_j\text{.}\) In other words, these are the subrectangles contained in
\(S\text{.}\) The interiors of the subrectangles
\(R'^\circ_j\) are disjoint and
\(V(R'^\circ_j) = V(R'_j)\text{.}\) Via
Exercise 10.3.16,
\begin{equation}
m^*\Bigl(\bigcup_{j=1}^\ell R'^\circ_j\Bigr)
=
\sum_{j=1}^\ell
V(R'^\circ_j) .
\end{equation}
Hence
\begin{equation}
m^*(S) \geq
m^*\Bigl(\bigcup_{j=1}^\ell R'_j\Bigr)
\geq
m^*\Bigl(\bigcup_{j=1}^\ell R'^\circ_j\Bigr)
=
\sum_{j=1}^\ell
V(R'^\circ_j)
=
\sum_{j=1}^\ell
V(R'_j)
=
L(P,\chi_S) \geq V(S) - \epsilon .
\end{equation}
Therefore \(m^*(S) \geq V(S)\) as well.